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Bis(12-crown-4)
Bis(12-crown-4)
- イオン電極用試薬
イオン電極用試薬―イオノフォア
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製品コードB021 Bis(12-crown-4)
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CAS番号80403-59-4
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化学名Bis[(12-crowN-4)methyl] 2-dodecyl-2-methylmalonate
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分子式・分子量C34H62O12=662.85
| 容 量 | メーカー希望 小売価格 |
富士フイルム 和光純薬 |
|---|---|---|
| 100 mg | ￥17,400 | 343-05021 |
| 500 mg | ￥56,200 | 349-05023 |
- ご購入方法
- お問い合わせ
マニュアル
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プロトコル
イオン濃度を電極で測りたい 
技術情報
溶解例
20 mg/100 μL（アセトニトリル）
参考文献
1) I. Ikeda, T. Katayama, M. Okahara and T. Shono, "Syntheses of Ester-type Bis-12-crown-4 Ethers and Their Complexing Abilities toward Sodium Cation", Tetrahedron Lett., 1981, 22(37), 3615.
2) H. Tamura, K. Kimura and T. Shono, "Coated Wire Sodium- and Potassium-selective Electrodes Based on Bis(crown ether) Compounds", Anal. Chem., 1982, 54, 1224.
3) T. Shono, M. Okahara, I. Ikeda, K. Kimura and H. Tamura, "Sodium-selective PVC Membrane Electrodes Based on Bis(12-crown-4)s", J. Electroanal. Chem., 1982, 132, 99.
4) H. Tamura, K. Kumami, K. Kimura and T. Shono, "Simultaneous Determination of Sodium and Potassium in Human Urine or Serum Using Coated-wire Ion-selective Electrodes Based on Bis(crown ether)s", Mikrochim. Acta, 1983, 2, 287.
5) H. Sakamoto, K. Kimura, Y. Koseki, M. Matsuo and T. Shono, "Lipophilic Bis(monoaza crown ether) Derivatives: Synthesis and Cation-complexing Properties", J. Org. Chem., 1986, 51, 4974.
6) T. Maruizumi, D. Wegmann, G. Suter, D. Ammann and W. Simon, "Neutral Carrier-based Na+ -selective Electrode for Application in Blood Serum", Mikrochim. Acta, 1986, I, 331.
7) H. Sakamoto, K. Kimura, Y. Koseki and T. Shono, "Highly Selective Cation Transport Through Membranes Containing Lipophilic Bis(monoazo-crown ether)s", J. Chem. Soc. Perkin Trans. 2, 1987, 1181.
8) N. Nakashima, I. Moriguchi, K. Nakano and M. Takagi, "Design of a Novel Bilayer System Responsive to Chemical Signals; Selective Discrimination of Na+ by a Spectroscopic Method", J. Chem. Soc., Chem. Commun., 1987, 617.
9) H. Widmer, S. Poitry and M. Tsacopoulos, "The Increase of Oxygen Consumption after a Flash of Light Is Tighly Coupled to Sodium Pumping in the Lateral Ocellus of Barnacle", J. Gen. Physiol., 1990, 96, 83.
10) M. Tanaka, H. Mizufune and T. Shono, "Evaluation of Complex Formation of Bis(12-crown-4)s with Sodium Picrate in Solution by 23Na NMR Spectroscopy, Chem. Lett., 1990, 1419.
11) Y. Shibutani, S. Mino, S. S. Long, T. Moriuchi-Kawakami, K. Yakabe and T. Shono, "Chiral Bis(12-crown-4)-based Electrodes for Sodium Ion", Chem. Lett., 1997, 49.
取扱条件
| 性状： | 本品は、無色～微黄色液体である。 |
|---|---|
| 純度(HPLC)： | 95.0%以上 |
| IRスペクトル： | 試験適合 |
| NMRスペクトル： | 試験適合 |
| 1.窒素置換 |
